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Blackening of Iron and Steel

Gun barrels and old hunting weapons burnished dark blue, black parts of measuring or optical instruments and various artistic steel products such as gratings, ashtrays, fireplace equipment, cast iron or steel fittings often have a beautiful black appearance. It is often necessary to retrofit a missing part and give it a colour afterwards. The dark or even black colour is given to cast iron and steel artificially by bathing it in appropriate solutions. This is called colouring or chemical dyeing and consists in the creation of a black or dark blue oxide layer on the metal surface. This layer plays not only a decorative role. Thanks to its chemical passivity, after additional greasing it quite effectively protects steel against corrosion. The quality and appearance of the layer depends primarily on the degree and thoroughness of preparation of the object's surface, which consists of grinding, polishing, degreasing and etching. If we want the object to shine after blackening, we must not forget about polishing. Unpolished objects will be dull after blackening, which is sometimes desirable.


[001] Blackened Mauser Kar 98K. The treatment increases resistance to corrosion and also reduces the possibility of light reflections from the weapon.

The simplest way to blacken steel is the so called flame blackening. Mechanically cleaned object is heated in the furnace or over the burner to about 200°C and then rubbed with a cloth on a stick dipped in vegetable oil (e.g. cooking oil). When blackened in this way, a very large amount of pungent smoke with an unpleasant smell is produced.
A much more durable blackening will be obtained by bathing the metal object for 30 minutes in a solution consisting of:

- water
- sodium hydroxide NaOH 400 g
- sodium nitrate NaNO2 600 g

The solution must first be heated to 140°C only then will it become liquid, because at room temperature it is thick and crumbly. The already prepared objects, suspended on an iron wire, are immersed in the hot bath for 30 minutes and frequently moved. To obtain a glossy black coating with high corrosion resistance it is best to use a two-stage blackening.

Bath I:
- sodium hydroxide NaOH 850 g
- potassium nitrate KNO3 25 g
- water to a volume of 1 dm3

Heat the bath in an iron or steel vessel to 140°C and immerse the blackened steel exhibits or products in it for 10 minutes. In order to thicken and consolidate the coating, the objects without rinsing are transferred to the vessel with bath II.

Bath II:
- sodium hydroxide NaOH 1100 g
- potassium nitrate KNO3 80 g
- water 950 cm3

The temperature of the bath is 155°C and the duration of blackening is 35 minutes. After finishing blackening in bath II the objects are carefully rinsed with water, dried in sawdust and lightly greased with oil or petroleum jelly. Well done two-stage blackening not only gives steel objects a shiny black colour but also increases resistance to corrosion.
Large steel objects can be blackened by rubbing with a suitable solution. To make such a solution, measure into a beaker:

-5 cm3 of denatured alcohol
-2 cm3 of nitric acid HNO3
-7,5 g iron(III) chloride FeCl3
-0,5 g copper(II) sulphate CuSO4 - 5H2O

The resulting solution is then saturated with a cotton wool swab and rubbed thoroughly onto the steel objects, after which the precipitate must dry and the solution must be applied to the surface. The item must then dry and be kept in steam for 30 minutes. A thorough rinsing in water, drying and greasing are the final steps of this treatment. The aim is to be able to choose the most suitable solution and blackening parameters, depending on the type of steel.
Steel objects which are not too dirty and have no corrosion products on the surface can be directly oxidised, i.e. blackened in concentrated alkaline solutions. Very greasy objects may be cleaned in organic solvents or alkaline solutions and pickled in sulphuric or hydrochloric acid with inhibitors. The bath for chemical oxidation of steel is a concentrated solution of NaOH with the addition of sodium nitrate or sodium nitrite, or both. The higher the carbon content of the steel product, the higher the process temperature must be and therefore the longer the blackening time. In order to increase corrosion resistance, oxidised steel products are additionally coated with oils or wax. However, as the oxide coated metal surface is better wettable with water and aqueous electrolyte solutions than with oil, which may cause the oil film to break on the surface of the product in such environments, it is necessary to immerse the product in a dilute aqueous soap solution before drying. This treatment will increase the wettability of the metal surface.


[002] Partially burnished, handmade knife.

Brunifying is a special, most noble type of steel blackening, used mainly for finishing the surfaces of expensive, precise objects, both new and antique. In this process, as in previous ones, a thin oxide layer is formed which gives the object an aesthetic dark blue colour and also protects it from corrosion. Bruising is a very tedious process, requiring great care and clean workmanship, but it produces very good results. It is used especially when replacing missing elements of old weapons. A very carefully polished, cleaned, thoroughly degreased and etched object is rinsed with denatured spirit, and after it dries it is moistened with a tampon dipped in the following solution:

-water 950 cm3
-concentrated hydrochloric acid HCl 1,5 cm3
-iron(III) chloride FeCl3 70 g
-iron(II) chloride FeCl2 10 g
-Mercury chloride HgCl2 2 g

Taking too much solution should be avoided. The swab should moisten the object evenly. A blackened object becomes darker in the eyes. After thoroughly wetting the whole object it is dried for 5-6 hours at 30-35°C and then for half an hour in a dryer or oven at 100-110°C. The next treatment is a bath for 30 minutes in a boiling solution of tannin, 10 g of which is dissolved in 1 dm3 of water. If, after removing the item from the tannin bath and drying it, a film forms on the surface of the item, it is cleaned with a soft brass wire brush.
The procedure of wetting the blackened object with the solution, drying and bathing in the tannin solution is repeated 3-5 times until an even, dark steel colour is obtained. A practical remark: all the time the object should be handled with pliers (not fingers) so as not to make it greasy.
Finally, the blackened object is boiled for 10-15 minutes in linseed oil and this is the end of the bruising process.
Other colours than navy blue and black cannot be permanently coloured on steel by chemical means. Copper is much more susceptible to colouring. Therefore, when we want to give a steel object a different, bright colour, firstly, copper layer is applied.





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